快速了解科研前沿动态，每天都有新想法！本内容主要对生命科学领域的一些期刊文章标题进行翻译，如果出现翻译错误请谅解。

1.Carbon is a primary constituent element of organic molecules, while metal catalysis is a basic tool in organic synthesis. In this work, the topics of carbon bonding and metal catalysis are linked together, and the concept of carbon-bonding metal catalysis is established as a new platform to regulate reactivity and selectivity issues.

碳是有机分子的主要组成元素，而金属催化是有机合成的基本工具。在这项工作中，碳键合和金属催化的主题联系在一起，并建立了碳键合金属催化的概念作为调节反应性和选择性问题的新平台。

2.On our cover art, we emphasize Nazarov cyclization/double ring expansions as a key strategy for synthesis of three phomopsene diterpenes. Light shown in the upper left corner represents the photochemical conditions. We also display the key intermediate to show the attractive pathway of this key strategy.

在我们的封面艺术中，我们强调纳扎罗夫环化/双环扩展作为合成三种拟茎二萜的关键策略。左上角显示的光代表光化学条件。我们还展示了关键中间体，以展示这一关键策略的有吸引力的途径。

3.Novel axially chiral biphenyl diphosphine (BridgePhos) ligands, with an ether chain bridge, have been developed, enabling a broader range of dihedral angles in their Rh-complexes, akin to the angles between the butterflies' wings on the cover art. The BridgePhos-Rh complex bearing the largest dihedral angle yielded the best catalytic results in asymmetric hydrogenations.

新型轴向手性联苯二膦 (BridgePhos) 配体已开发出来，具有醚链桥，可在其 Rh 配合物中实现更广泛的二面角，类似于封面上蝴蝶翅膀之间的角度。具有最大二面角的 BridgePhos-Rh 配合物在不对称氢化反应中产生了最好的催化效果。

4.A catalytically efficient acidic RNA-cleaving deoxyribozyme, selected from a random-sequence DNA library by in vitro selection, was activated by a specific bacterial pathogen using monovalent metal ions as required cofactors.

通过体外选择从随机序列 DNA 文库中选出的催化高效的酸性 RNA 裂解脱氧核酶，被特定的细菌病原体使用单价金属离子作为所需的辅助因子激活。

5.Azulene, an archetypal anti-Kasha fluorophore, emits only from its second excited singlet state (S2). The cover shows an artistic representation of azulene in three different electronic states, S0, S1, and S2.  While it is emissive from aromatic S2, it alleviates its antiaromaticity in S1 by a conical intersection.

Azulene 是一种典型的抗 Kasha 荧光团，仅从其第二激发单线态 (S2) 发射。封面展示了甘菊环在三种不同电子态（S0、S1 和 S2）下的艺术表现。虽然它是从芳香族 S2 发射的，但它通过圆锥形相交减轻了 S1 中的反芳香性。

6.An ordered lipid phase domain, shown with red head groups, induces order in the apposed fluid lipids, shown with green head groups. (Cover art credit to T. A. Enoki.)

有序的脂质相域（以红色头基团显示）诱导了相应的流体脂质（以绿色头基团显示）的有序性。 （封面艺术由 TA Enoki 提供。）

7.Stepwise sulfite reduction is achieved on a dinuclear ruthenium complex, leading to hydrogen sulfide. This mirrors the enzymatic function of dissimilatory sulfite reductases (SO32– + 8H+ + 6e– → H2S + 3H2O) in the global sulfur cycle.

在双核钌络合物上实现逐步亚硫酸盐还原，产生硫化氢。这反映了全局硫循环中异化亚硫酸盐还原酶 (SO32– + 8H+ + 6e– → H2S + 3H2O) 的酶功能。

8.A liposome-based split-and-mix PROTAC system (LipoSM-PROTAC) could selectively and efficiently degrade protein of interests (POIs). The LipoSM-PROTAC has unique advantages such as adjustable ligand ratios, good biocompatibility, potential for targeting multiple POIs, and other chimera-type applications.

基于脂质体的分离混合 PROTAC 系统 (LipoSM-PROTAC) 可以选择性且有效地降解目标蛋白 (POI)。 LipoSM-PROTAC具有独特的优势，例如可调节的配体比例、良好的生物相容性、针对多个POI的潜力以及其他嵌合型应用。

9.Charting new horizons: unveiling the potential of ternary chalcogenides for advanced photovoltaic materials.

开拓新视野：揭示三元硫属化物在先进光伏材料中的潜力。

10.Self-assembling senolytics targeting mitochondria of senescent cells with an intracellular oligomerization have been developed. Oligomerization via ROS-responsive disulfide formation results in a nanoassembly with a stable α-helical structure, which can disrupt the mitochondrial membrane. This supramolecular senolytic can induce apoptosis of senescent cells selectively, leading to treatment of age-related diseases.

已经开发出针对衰老细胞线粒体并进行细胞内寡聚化的自组装 senolytics。通过 ROS 响应的二硫键形成进行寡聚化，形成具有稳定 α 螺旋结构的纳米组装体，该结构可以破坏线粒体膜。这种超分子senolytic可以选择性诱导衰老细胞凋亡，从而治疗与年龄相关的疾病。

11.Anisotropic inter-chain interactions in quasi-one-dimensional van der Waals solids, if controlled, lead to dimensionally resolved nanostructures. In this work, we show that gaining synthetic control over these interactions in the model Sb2S3 phase leads to crystallographically well-defined nanowires, nanoribbons, and nanosheets with drastically altered photophysical properties.

准一维范德华固体中的各向异性链间相互作用如果受到控制，就会产生尺寸分辨的纳米结构。在这项工作中，我们表明，对模型 Sb2S3 相中的这些相互作用进行综合控制可以产生晶体学上明确的纳米线、纳米带和纳米片，这些纳米线、纳米带和纳米片的光物理性质发生了巨大的改变。

12.Cytochrome c oxidase is the terminal enzyme in the electron transfer chain in mitochondria. It binds a diatomic ligand, O2, in a unique binuclear center and reduces it to water. Its ligand migration trajectory was explored in real time by time-resolved serial femtosecond crystallography following photodissociation for the first time.

细胞色素c氧化酶是线粒体电子传递链的末端酶。它将双原子配体 O2 结合在独特的双核中心并将其还原为水。首次通过光解离后的时间分辨串行飞秒晶体学实时探索其配体迁移轨迹。

13.An unprecedented two-electron oxidation at a molecular cerium(II) compound by pyridine N-oxide yields a multiply bound cerium(IV) terminal oxo complex.

吡啶 N-氧化物对分子铈 (II) 化合物进行前所未有的双电子氧化，产生多重结合的铈 (IV) 末端氧配合物。

14.Coupling a comproportionation process and an auxiliary oxidation or reduction process results in a stoichiometrically autocatalytic cycle. Such autocatalytic cycles are identified in all element groups in the periodic table and have the potential to underpin abiotic ecological interactions that may lead to life-like systems on different astronomical objects.

将歧化过程与辅助氧化或还原过程耦合导致化学计量自催化循环。这种自催化循环在元素周期表中的所有元素组中都有发现，并且有可能支持非生物生态相互作用，从而可能在不同的天体上形成类似生命的系统。

15.Χ6Ι62+ is a double (π and σ) 2D-aromatic species. Similarly, B12Ι12 has an inner Wade-Mingos aromatic cage and an outer I12 circle with some of the typical properties of aromatic compounds. However, this I12 surface does not bring stability; therefore, [B12Ι12] cannot be considered fully doubly 3D-aromatic.

Χ6I62+ 是双（π 和 σ）2D-芳香族物质。类似地，B12I12 具有内部 Wade-Mingos 芳香笼和外部 I12 环，具有芳香族化合物的一些典型特性。然而，这个I12表面并没有带来稳定性；因此，[B12I12] 不能被视为完全双 3D 芳香族。

16.Nanoparticles composed of both silica and nucleic acids are prepared through a one-step bottom-up process. Specific functionalities can be incorporated into the particles, depending on the type and sequence of the nucleic acid. Exposure to enzymes or biomolecules triggers the degradation of the particles and the release of the oligonucelotides.

由二氧化硅和核酸组成的纳米颗粒是通过一步自下而上的过程制备的。根据核酸的类型和序列，可以将特定功能掺入颗粒中。暴露于酶或生物分子会引发颗粒的降解和寡核苷酸的释放。

17.A peptide-modifying radical S-adenosylmethionine enzyme can catalyze three distinct post-translational modifications: ether cross-link, C-C cross-link, and formylglycine formation. These diverse catalytic outcomes are simply dictated by the single amino acid in the peptide substrate, highlighting the intriguing catalytic promiscuity of these remarkable enzymes and their amazing ability in the biosynthesis of antibacterial peptide natural products.

肽修饰自由基 S-腺苷甲硫氨酸酶可以催化三种不同的翻译后修饰：醚交联、CC 交联和甲酰甘氨酸形成。这些不同的催化结果仅由肽底物中的单个氨基酸决定，突显了这些非凡酶的令人着迷的催化混杂性及其在抗菌肽天然产物生物合成中的惊人能力。

18.Artistic view of the self-assembly process between peptide-based supramolecular building blocks and mRNA to produce nanotube-shaped carriers for mRNA delivery that can be developed into thermodynamically stable mRNA vaccines and therapeutics.

基于肽的超分子构件和 mRNA 之间的自组装过程的艺术视图，以产生用于 mRNA 递送的纳米管状载体，该载体可开发成热力学稳定的 mRNA 疫苗和治疗剂。

19.Boron atom substitutions in aluminum nanoclusters (Aln) render the resulting Aln-1B nanoclusters chemically active or inactive, depending on the exohedral or endohedral B-atom placement. Notably, oxidative reactivity significantly enhances at Al6B and Al11B2 in the exohedral B atom sites, especially when an extra B atom replaces the endohedral B@Al12 superatom.

铝纳米团簇 (Aln) 中的硼原子取代使所得 Aln-1B 纳米团簇具有化学活性或非活性，具体取决于外面或内面 B 原子的位置。值得注意的是，Al6B 和 Al11B2 外面 B 原子位点的氧化反应活性显着增强，特别是当额外的 B 原子取代内面 B@Al12 超原子时。

20.Treatment of formamidinates with perfluoroarenes and perfluoroalkenes leads to a unique [3+2] cycloaddition in the presence of Lewis acidic additives (such as LiBF4 and BF3•Et2O). The resultant polyfluorinated imidazolium salts are good precursors for the corresponding polyfluorinated N-heterocyclic carbenes.

在路易斯酸性添加剂（例如LiBF4 和BF3·Et2O）存在下，用全氟芳烃和全氟烯烃处理甲脒酯会产生独特的[3+2]环加成反应。所得多氟化咪唑鎓盐是相应多氟化N-杂环卡宾的良好前体。

21.Photocatalytic ATRP Depolymerization: Temporal Control at Low ppm of Catalyst Concentration.

光催化 ATRP 解聚：低 ppm 催化剂浓度下的时间控制。

22.Enantioselective Synthesis of Chiral Cyclobutenes Enabled by Brønsted Acid-Catalyzed Isomerization of BCBs.

通过布朗斯台德酸催化 BCB 异构化实现手性环丁烯的对映选择性合成。

23.π-Aromaticity Dominating in a Saturated Ring: Neutral Aromatic Silicon Analogues of Cyclobutane-1,3-diyls.

π-芳香性在饱和环中占主导地位：环丁烷-1,3-二基的中性芳香族硅类似物。

24.Cryo-annealing of Photoreduced CdS Quantum Dot–Nitrogenase MoFe Protein Complexes Reveals the Kinetic Stability of the E4(2N2H) Intermediate.

光还原 CdS 量子点-固氮酶 MoFe 蛋白复合物的低温退火揭示了 E4(2N2H) 中间体的动力学稳定性。

25.Total Syntheses of Polycyclic Diterpenes Phomopsene, Methyl Phomopsenonate, and iso-Phomopsene via Reorganization of C–C Single Bonds.

通过 C-C 单键重组全合成多环二萜 Phomopsene、Phomopsenonate 和 iso-Phomopsene。

26.Rh-Catalyzed Enantioselective Desymmetric Hydrogenation of α-Acetamido-1,3-indanediones Using Ether-Bridged Biphenyl Diphosphine Ligands.

使用醚桥联苯二膦配体进行 Rh 催化的 α-乙酰氨基-1,3-茚满二酮对映选择性不对称氢化。

27.Revisiting Coley’s Toxins: Immunogenic Cardiolipins from Streptococcus pyogenes.

重新审视科利毒素：来自化脓性链球菌的免疫原性心磷脂。

28.One-Pot Synthesis of Sulfonamides from Unactivated Acids and Amines via Aromatic Decarboxylative Halosulfonylation.

通过芳香脱羧卤磺酰化从未活化的酸和胺一锅法合成磺酰胺。

29.Total Synthesis of Njaoamine C by Concurrent Macrocycle Formation.

通过同时大环形成全合成 Njaoamine C。

30.Impersonating a Superconductor: High-Pressure BaCoO3, an Insulating Ferromagnet.

模拟超导体：高压 BaCoO3，一种绝缘铁磁体。

31.High Electric Fields on Water Microdroplets Catalyze Spontaneous and Fast Reactions in Halogen-Bond Complexes.

水微滴上的高电场催化卤素键配合物中的自发快速反应。

32.Selective Water Pore Recognition and Transport through Self-Assembled Alkyl-Ureido-Trianglamine Artificial Water Channels.

通过自组装烷基脲基三胺人工水通道选择性水孔识别和运输。

33.Naked-Eye Thiol Analyte Detection via Self-Propagating, Amplified Reaction Cycle.

通过自传播放大反应循环进行肉眼硫醇分析物检测。

34.Silanol-Engineered Nonclassical Growth of Zeolite Nanosheets from Oriented Attachment of Amorphous Protozeolite Nanoparticles.

通过非晶质原沸石纳米颗粒的定向附着来进行硅烷醇工程的沸石纳米片的非经典生长。

35.High-Entropy Laminates with High Ion Conductivities for High-Power All-Solid-State Lithium Metal Batteries.

用于高功率全固态锂金属电池的具有高离子电导率的高熵层压板。

36.Helicase Activity Modulation with On-Demand Light-Based Conformational Control.

解旋酶活性调节与按需光构象控制。

37.Creating Order in Ultrastable Phosphonate Metal–Organic Frameworks via Isolable Hydrogen-Bonded Intermediates.

通过可分离的氢键中间体在超稳定膦酸盐金属有机框架中创造秩序。

38.Engineering Molecular Heterostructured Catalyst for Oxygen Reduction Reaction.

用于氧还原反应的工程分子异质结构催化剂。

39.General Approach to Construct C–C Single Bond-Linked Covalent Organic Frameworks.

构建 C-C 单键连接的共价有机框架的一般方法。

40.Constructing Antiretroviral Supramolecular Polymers as Long-Acting Injectables through Rational Design of Drug Amphiphiles with Alternating Antiretroviral-Based and Hydrophobic Residues.

通过合理设计具有交替抗逆转录病毒和疏水残基的药物两亲物，将抗逆转录病毒超分子聚合物构建为长效注射剂。

41.Solid-Phase Compatible Silane-Based Cleavable Linker Enables Custom Isobaric Quantitative Chemoproteomics.

固相兼容的基于硅烷的可裂解接头可实现定制同量异位定量化学蛋白质组学。

42.CO2 Reduction to Methane and Ethylene on a Single-Atom Catalyst: A Grand Canonical Quantum Mechanics Study.

在单原子催化剂上将二氧化碳还原为甲烷和乙烯：一项大经典量子力学研究。

43.Tailoring Interlayer Charge Transfer Dynamics in 2D Perovskites with Electroactive Spacer Molecules.

使用电活性间隔分子定制二维钙钛矿中的层间电荷转移动力学。

44.Good Vibrations Report on the DNA Quadruplex Binding of an Excited State Amplified Ruthenium Polypyridyl IR Probe.

关于激发态放大钌聚吡啶红外探针的 DNA 四链体结合的良好振动报告。

45.Biosynthetic Origin of the Octose Core and Its Mechanism of Assembly during Apramycin Biosynthesis.

安普霉素生物合成过程中八糖核心的生物合成起源及其组装机制。

46.In Vitro Selection of M2+-Independent, Fast-Responding Acidic Deoxyribozymes for Bacterial Detection.

用于细菌检测的 M2+ 独立、快速响应的酸性脱氧核酶的体外选择。

47.Photosalience and Thermal Phase Transitions of Azobenzene- and Crown Ether-Based Complexes in Polymorphic Crystals.

多晶型晶体中偶氮苯和冠醚基配合物的光致性和热相变。

48.Cation Substitution Strategy for Developing Perovskite Oxide with Rich Oxygen Vacancy-Mediated Charge Redistribution Enables Highly Efficient Nitrate Electroreduction to Ammonia.

用于开发具有富氧空位介导的电荷重新分布的钙钛矿氧化物的阳离子取代策略可实现高效的硝酸盐电还原为氨。

49.Isoreticular Expansion and Linker-Enabled Control of Interpenetration in Titanium–Organic Frameworks.

钛有机框架中的等网状扩张和连接体对相互渗透的控制。

50.Variations on the Bergman Cyclization Theme: Electrocyclizations of Ionic Penta-, Hepta-, and Octadiynes.

伯格曼环化主题的变体：离子五、七和辛二炔的电环化。

51.Ru–Cu Nanoheterostructures for Efficient Hydrogen Evolution Reaction in Alkaline Water Electrolyzers.

用于碱性水电解槽中高效析氢反应的 Ru-Cu 纳米异质结构。

52.Single-Atom Cr–N4 Sites with High Oxophilicity Interfaced with Pt Atomic Clusters for Practical Alkaline Hydrogen Evolution Catalysis.

具有高亲氧性的单原子 Cr-N4 位点与 Pt 原子簇相互作用，用于实用的碱性析氢催化。

53.Computational Design and Experimental Validation of Enzyme Mimicking Cu-Based Metal–Organic Frameworks for the Reduction of CO2 into C2 Products: C–C Coupling Promoted by Ligand Modulation and the Optimal Cu–Cu Distance.

用于将 CO2 还原为 C2 产品的酶模拟铜基金属有机框架的计算设计和实验验证：配体调制和最佳 Cu-Cu 距离促进 C-C 偶联。

54.Mesoporous Nano-Badminton with Asymmetric Mass Distribution: How Nanoscale Architecture Affects the Blood Flow Dynamics.

具有不对称质量分布的介孔纳米羽毛球：纳米级结构如何影响血流动力学。

55.Spatially and Chemically Resolved Visualization of Fe Incorporation into NiO Octahedra during the Oxygen Evolution Reaction.

析氧反应过程中 Fe 与 NiO 八面体结合的空间和化学分辨可视化。

56.Bis(9-Boraphenanthrene) and Its Stable Biradical.

Bis(9-Boraphenanthrene) 及其稳定的双自由基。

57.Kilogram-Scale Fabrication of a Robust Olefin-Linked Covalent Organic Framework for Separating Ethylene from a Ternary C2 Hydrocarbon Mixture.

公斤级制造用于从三元 C2 烃混合物中分离乙烯的鲁棒烯烃连接共价有机框架。

58.Molecular Self-Assembly in Conductive Covalent Networks for Selective Nitrate Electroreduction to Ammonia.

导电共价网络中的分子自组装用于选择性硝酸盐电还原为氨。

59.Quantitative Operando7Li NMR Investigations of Silicon Anode Evolution during Fast Charging and Extended Cycling.

快速充电和长时间循环期间硅阳极演化的定量 Operando7Li NMR 研究。

60.Chemical Synthesis of Microtubule-Associated Protein Tau.

微管相关蛋白 Tau 的化学合成。

61.Chemical Modification of Oxidized Polyethylene Enables Access to Functional Polyethylenes with Greater Reuse.

氧化聚乙烯的化学改性能够获得具有更大重复利用性的功能性聚乙烯。

62.Hydrocarbon Degradation by Contact with Anoxic Water Microdroplets.

与缺氧水微滴接触导致碳氢化合物降解。

63.Interfacial Supra-Assembly of Copolymer Nanoparticles Enables the Formation of Nanocomposite Crystals with a Tunable Internal Structure.

共聚物纳米颗粒的界面超组装能够形成具有可调内部结构的纳米复合晶体。

64.Carbon-Bonding Metal Catalysis (CBMC): A Supramolecular Complex Directs Structural-Isomer Selection in Gold-Catalyzed Reactions.

碳键合金属催化 (CBMC)：超分子配合物指导金催化反应中的结构异构体选择。

65.Enantioselective Total Syntheses of Cassane Furanoditerpenoids and Their Stimulation of Cellular Respiration in Brown Adipocytes.

卡桑呋喃二萜类化合物的对映选择性全合成及其对棕色脂肪细胞细胞呼吸的刺激。

66.Excited-State (Anti)Aromaticity Explains Why Azulene Disobeys Kasha’s Rule.

激发态（反）芳香性解释了为什么甘菊环违反卡莎规则。

67.Direct Observation of Triplet States in the Isomerization of Alkenylboronates by Energy Transfer Catalysis.

通过能量转移催化直接观察烯基硼酸酯异构化中的三重态。

68.Reactivity Prediction of Cu-Catalyzed Halogen Atom Transfer Reactions Using Data-Driven Techniques.

使用数据驱动技术预测铜催化卤素原子转移反应的反应性。

69.Domino Reactions Enabling Sulfur-Mediated Gradient Interphases for High-Energy Lithium Batteries.

多米诺反应为高能锂电池提供硫介导的梯度界面相。

70.Twists and Puckers: Tuning Crystal Chemistry in the La(AuxGe1–x)2 Compositional Series.

扭曲和褶皱：调整 La(AuxGe1–x)2 组成系列中的晶体化学。

71.Photocatalytic Carboxylate to Sulfinamide Switching Delivers a Divergent Synthesis of Sulfonamides and Sulfonimidamides.

光催化羧酸盐到亚磺酰胺的转换提供了磺酰胺和磺酰亚胺的不同合成。

72.Metal/ADP Complexes Promote Phosphorylation of Ribonucleotides.

金属/ADP 复合物促进核糖核苷酸的磷酸化。

73.Synthesis of Allenes by Hydroalkylation of 1,3-Enynes with Ketones Enabled by Cooperative Catalysis.

协同催化下 1,3-烯炔与酮的加氢烷基化合成联烯。

74.Promoter R-Loops Recruit U2AF1 to Modulate Its Phase Separation and RNA Splicing.

启动子 R 环招募 U2AF1 来调节其相分离和 RNA 剪接。

75.Reductive Competition Effect-Derived Solid Electrolyte Interphase with Evenly Scattered Inorganics Enabling Ultrahigh Rate and Long-Life Span Sodium Metal Batteries.

还原竞争效应衍生的固体电解质界面与均匀分散的无机物可实现超高倍率和长寿命钠金属电池。

76.Dicopper(I) Sites Confined in a Single Metal–Organic Layer Boosting the Electroreduction of CO2 to CH4 in a Neutral Electrolyte.

限制在单个金属有机层中的二铜 (I) 位点促进中性电解质中 CO2 电还原为 CH4。

77.Supramolecular Transistors with Quantum Interference Effect.

具有量子干涉效应的超分子晶体管。

78.Selenophene-Based 2D Ruddlesden-Popper Perovskite Solar Cells with an Efficiency Exceeding 19%.

基于硒吩烯的二维 Ruddlesden-Popper 钙钛矿太阳能电池，效率超过 19%。

79.Correction to “Layered Semiconductor Cr0.32Ga0.68Te2.33 with Concurrent Broken Inversion Symmetry and Ferromagnetism: A Bulk Ferrovalley Material Candidate”.

对“具有并发破缺反演对称性和铁磁性的层状半导体 Cr0.32Ga0.68Te2.33：块体铁谷材料候选”的更正。

80.In Pursuit of the Exceptional: Research Directions for Machine Learning in Chemical and Materials Science.

追求卓越：化学和材料科学中机器学习的研究方向。

81.An Unexpected Driving Force for Lipid Order Appears in Asymmetric Lipid Bilayers.

不对称脂质双层中出现脂质有序的意外驱动力。

82.Tripodal Organic Cages with Unconventional CH···O Interactions for Perchlorate Remediation in Water.

具有非常规CH·O相互作用的三足有机笼用于水中高氯酸盐修复。

83.Stepwise Sulfite Reduction on a Dinuclear Ruthenium Complex Leading to Hydrogen Sulfide.

双核钌络合物的逐步亚硫酸盐还原产生硫化氢。

84.The Dynamic Lewis Acid–Carbene Hybrid: Pushing the Electrophilicity of Carbenes to the Limit.

动态路易斯酸-卡宾杂化物：将卡宾的亲电性推向极限。

85.Photocatalytic Anti-Markovnikov Hydroamination of Alkenes with Primary Heteroaryl Amines.

烯烃与杂芳基伯胺的光催化反马尔可夫尼科夫氢胺化。

86.1,2-Redox Transpositions of Tertiary Amides.

叔酰胺的 1,2-氧化还原转位。

87.Enantioselective Synthesis of Cyclobutane Derivatives via Cascade Asymmetric Allylic Etherification/[2 + 2] Photocycloaddition.

通过级联不对称烯丙基醚化/[2 + 2]光环加成对映选择性合成环丁烷衍生物。

88.Convergent Total Synthesis of (−)-Cyclopamine.

(−)-环巴胺的收敛全合成。

89.31P Nuclear Magnetic Resonance Spectroscopy as a Probe of Thorium–Phosphorus Bond Covalency: Correlating Phosphorus Chemical Shift to Metal–Phosphorus Bond Order.

31P 核磁共振波谱作为钍磷键共价探针：将磷化学位移与金属磷键顺序相关联。

90.Precise Equilibrium Structure of Benzene.

苯的精确平衡结构。

91.Tuning Crystallinity and Stacking of Two-Dimensional Covalent Organic Frameworks through Side-Chain Interactions.

通过侧链相互作用调节二维共价有机框架的结晶度和堆叠。

92.Large Perpendicular Magnetic Anisotropy Induced by an Intersite Charge Transfer in Strained EuVO2H Films.

应变 EuVO2H 薄膜中位点间电荷转移引起的大垂直磁各向异性。

93.Disorder and Oxide Ion Diffusion Mechanism in La1.54Sr0.46Ga3O7.27 Melilite from Nuclear Magnetic Resonance.

核磁共振显示 La1.54Sr0.46Ga3O7.27 黄长石中的无序和氧化物离子扩散机制。

94.Assessing the Role of R120 in the Gating of CrChR2 by Time-Resolved Spectroscopy from Femtoseconds to Seconds.

通过从飞秒到秒的时间分辨光谱评估 R120 在 CrChR2 门控中的作用。

95.Ratiometric Fluorescent Sensors Illuminate Cellular Magnesium Imbalance in a Model of Acetaminophen-Induced Liver Injury.

比例荧光传感器揭示对乙酰氨基酚引起的肝损伤模型中的细胞镁失衡。

96.Overcoming the Potential Window-Limited Functional Group Compatibility by Alternating Current Electrolysis.

通过交流电解克服潜在的窗口限制官能团兼容性。

97.Selective Protein of Interest Degradation through the Split-and-Mix Liposome Proteolysis Targeting Chimera Approach.

通过针对嵌合体方法的拆分和混合脂质体蛋白水解选择性降解感兴趣的蛋白质。

98.Methylated Nucleotide-Based Proteolysis-Targeting Chimera Enables Targeted Degradation of Methyl-CpG-Binding Protein 2.

基于甲基化核苷酸的蛋白水解靶向嵌合体能够靶向降解甲基-CpG 结合蛋白 2。

99.Polymer Networks with Cubic, Mixed Pd(II) and Pt(II) M6L12 Metal–Organic Cage Junctions: Synthesis and Stress Relaxation Behavior.

具有立方、混合 Pd(II) 和 Pt(II) M6L12 金属有机笼式连接的聚合物网络：合成和应力松弛行为。

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