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【标题速读】【Angew】【2023年】【6月】
Rt_Cola
编辑于 2023年12月19日 06:05
收录于文集
共301篇

快速了解科研前沿动态,每天都有新想法!本内容主要对生命科学领域的一些期刊文章标题进行翻译,如果出现翻译错误请谅解。

1.Using advanced analytical techniques based on synchrotron and electron microscopy as described in their Research Article (e202300943), Pengcheng Liu, David Mitlin et al. were able to "see&#​34; and understand the growth of body centered cubic potassium metal dendrites, depicted in the cover picture as corals growing underwater and away from normal sight. This is represented by the light rays shining down from above. The fish are peacock bass, indigenous to South America but also found in the warmer waters of Florida.

Peng Cheng Liu、David Mitlin 等人使用基于同步加速器和电子显微镜的先进分析技术,如其研究文章 (e202300943) 中所述。我们能够“看到”并理解体心立方钾金属树突的生长,封面图片中描绘的珊瑚在水下生长,远离正常视线。这是由从上方照射下来的光线表示的。这种鱼是孔雀鲈,原产于南美洲,但在佛罗里达州温暖的水域也有发现。

2.Two cooperative robotic arms [Rh/P(O)nBu2] are in the process of activating and breaking C−F bonds to create C−H bonds. In their Research Article (e202219127), Christophe Werlé and co-workers developed a molecular template based on these design elements to improve the catalytic hydrodefluorination of perfluoroarenes across a wide range of substrates.

两个协作机械臂 [Rh/P(O)nBu2] 正在激活和破坏 C−F 键以创建 C−H 键。在他们的研究文章 (e202219127) 中,Christophe Werlé 和同事开发了一种基于这些设计元素的分子模板,以改善全氟芳烃在各种基材上的催化加氢脱氟反应。

3.Inspired by the metamorphosis development of glowing octopus, Wei Lu, Wenqin Wang, Tao Chen et al. demonstrate in their Research Article (e202300417) a strategy to replicate the structure-editing capacity of natural organisms in soft artificial actuators/robots. The environment-interactive morphology/pattern information can be imitated to produce conceptually new environment-interactive information encryption systems.

受发光章鱼变态发育的启发,Wei Lu、Wenqin Wang、Tao Chen等人。在他们的研究文章(e202300417)中展示了一种在软人工执行器/机器人中复制自然生物体结构编辑能力的策略。可以模仿环境交互形态/图案信息以产生概念上新的环境交互信息加密系统。

4.The “ortho-benzoquinone spaceship” and the “phosphorus mononitride meteor stream” fly together towards the green aurora at the Earth′s North Pole. The green aurora symbolizes the light used to release PN. The spaceship symbolizes ortho-benzoquinone: the six facets represent the carbon atoms in ortho-benzoquinone and the two red facets represent the oxygen atoms, as illustrated by Artur Mardyukov and co-workers in their Research Article (e202300761).

“邻苯醌飞船”与“氮化磷流星流”一起飞向地球北极的绿色极光。绿色极光象征着用于释放PN的光。宇宙飞船象征着邻苯醌:六个面代表邻苯醌中的碳原子,两个红色面代表氧原子,如 Artur Mardyukov 及其同事在他们的研究文章 (e202300761) 中所示。

5.Covalent Organic Frameworks. The transformation of imine cages into a covalent organic framework film through dynamic covalent chemistry at the liquid–liquid interface is reported by Abhijit Patra et al. in their Research Article (e202219083).

共价有机框架。 Abhijit Patra 等人在他们的研究文章(e202219083)中报道了通过液-液界面的动态共价化学将亚胺笼转化为共价有机骨架膜。

6.Photochemistry. In their Communication (e202303435), Tsuyoshi Mita et al. report a method for the diphosphination of [1.1.1]propellane using visible light.

光化学。在他们的通讯(e202303435)中,Tsuyoshi Mita 等人报告一种使用可见光对[1.1.1]丙烷进行二磷化的方法。

7.Fluorescence lifetime imaging is a powerful technique. In their Research Article (e202300682), Sebastian Kruss et al. used single-walled carbon nanotubes (SWCNTs) as fluorescent probes/sensors for biomolecules in the near infrared (NIR) tissue transparency window. The SWCNTs were functionalized with DNA to render them selective for the important neurotransmitter dopamine. Time correlated single photon counting in a confocal microscope was used to read out fluorescence lifetime, which changed with dopamine concentration. This approach enabled the measurement of dopamine around cells. Thus, the fluorescence lifetime of SWCNTs becomes a new sensing strategy for bio(molecules).

荧光寿命成像是一项强大的技术。 Sebastian Kruss 等人在他们的研究文章 (e202300682) 中使用单壁碳纳米管(SWCNT)作为近红外(NIR)组织透明窗口中生物分子的荧光探针/传感器。 SWCNT 通过 DNA 进行功能化,使其对重要的神经递质多巴胺具有选择性。使用共聚焦显微镜中的时间相关单光子计数来读出荧光寿命,该寿命随多巴胺浓度而变化。这种方法能够测量细胞周围的多巴胺。因此,单壁碳纳米管的荧光寿命成为一种新的生物(分子)传感策略。

8.Cellulose nanocrystals (CNCs) have been captured inside a zinc-containing microporous organic polymer (MOP) network through sacrificial templating with zeolitic imidazolate framework (ZIF-8) crystals. In their Research Article (e202300960), Mark MacLachlan et al. report the synthesis of novel MOP@CNC hybrid materials with a ship-in-a-bottle structure, and demonstrate their use as heterogeneous catalysts for CO2 conversion.

通过沸石咪唑酯骨架 (ZIF-8) 晶体的牺牲模板,纤维素纳米晶体 (CNC) 被捕获在含锌微孔有机聚合物 (MOP) 网络内。 Mark MacLachlan 等人在他们的研究文章 (e202300960) 中报道了具有瓶中船结构的新型MOP@CNC混合材料的合成,并展示了它们作为二氧化碳转化的非均相催化剂的用途。

9.A ruthenium-based photocage that can be activated by 760 nm NIR light via single-photon pathway is reported by Xuezhao Li, Wen Sun et al. in their Research Article (e202218768). The photocage was engineered into amphiphilic block copolymers, forming nanoparticles via self-assembly, which release the ruthenium complex-based photocages to inhibit tumor proliferation in vivo upon exposure to NIR light.

Xuezhao Li、Wen Sun 等人在他们的研究文章(e202218768)中报道了一种基于钌的光笼,可以通过单光子途径被 760 nm 近红外光激活。该光笼被设计成两亲性嵌段共聚物,通过自组装形成纳米颗粒,在暴露于近红外光时释放基于钌络合物的光笼以抑制体内肿瘤增殖。

10.Graphene nanoribbons with unique edge and termini structures were synthesized on an Au(111) surface using 7-bromo-12-(10-bromoanthracen-9-yl)tetraphene as the molecular precursor. The nonplanar zigzag termini demonstrated Kondo resonance even on bare Au(111), as reported by Atsushi Ishikawa, Akimitsu Narita, Shigeki Kawai and co-workers in their Research Article (e202302534).

以7-溴-12-(10-溴蒽-9-基)四苯为分子前驱体,在Au(111)表面合成了具有独特边缘和末端结构的石墨烯纳米带。正如 Atsushi Ishikawa、Akimitsu Narita、Shigeki Kawai 及其同事在他们的研究文章 (e202302534) 中报道的那样,非平面之字形末端甚至在裸露的 Au(111) 上也表现出近藤共振。

11.Electrocatalysis. In their Research Article (e202301408), Zhao-Qing Liu et al. report the activation of lattice oxygen in spinel ZnCo2O4 through filling oxygen vacancies with fluorine, thus resulting in a highly active catalyst for electrocatalytic oxygen evolution.

电催化。在他们的研究文章 (e202301408) 中,Zhao-Qing Liu 等人报告通过用氟填充氧空位来激活尖晶石 ZnCo2O4 中的晶格氧,从而产生用于电催化析氧的高活性催化剂。

12.Allylation. In their Communication (e202301839), Lukas J. Gooßen et al. report a simple manganese catalyst for the ortho-C−H allylation of benzoic acids. The reaction can be combined with an in situ decarboxylation, giving access to allylarenes in substitution patterns that are otherwise hard to obtain.

烯丙基化。在他们的通讯 (e202301839) 中,Lukas J. Gooßen 等人。报道了一种用于苯甲酸邻位 C−H 烯丙基化的简单锰催化剂。该反应可以与原位脱羧结合,以其他方式难以获得的取代模式获得烯芳基。

13.The copolymerization of kinetically trapped states of tetraphenylethylene containing glycine (TPE-G) and/or D-/L-alanine moieties leads to the formation of supramolecular multi-block copolymers, such as B-A-B, A-B-A-B-A, and C-B-A-B-C patterns (BCPs; tri- and penta-blocks) by a chain-growth process. The chirality of the supramolecular BCPs was not only successfully controlled by the chiral seed, but it also transferred to an achiral component during the chain-growth polymerization, as reported Sung Ho Jung, Jong Hwa Jung et al. in their Research Article (e202300913).

含有甘氨酸(TPE-G)和/或D-/L-丙氨酸部分的四苯乙烯动力学捕获态的共聚导致超分子多嵌段共聚物的形成,例如BAB、ABABA和CBABC模式(BCP;三-和五块)通过链增长过程。据 Sung Ho Jung、Jong Hwa Jung 等人在他们的研究文章(e202300913)中报道,超分子 BCP 的手性不仅通过手性种子成功控制,而且还在链增长聚合过程中转移到非手性组分。

14.Hydrogel preparation under NIR light via a photoinduced RAFT polymerization catalyzed by tetrasulfonated zinc phthalocyanine is reported by Cyrille Boyer et al. in their Research Article (e202302451). Exploiting enhanced penetration of NIR light, photoinduced gelation is effectively performed through barriers. Thiocarbonylthio groups embedded in hydrogel networks facilitate the reactivation of polymer chains under NIR wavelengths, enabling the photoinduced healing of hydrogels through non-transparent barriers.

Cyrille Boyer 等人在他们的研究文章(e202302451)中报道了在近红外光下通过四磺化锌酞菁催化的光诱导 RAFT 聚合制备水凝胶。利用近红外光增强的穿透力,可以有效地穿过屏障进行光诱导凝胶化。嵌入水凝胶网络中的硫代羰基硫基团有助于在近红外波长下重新激活聚合物链,从而实现水凝胶穿过不透明屏障的光诱导愈合。

15.The determination of nanometer-scale distances in solution is an enormous challenge. In their Research Article (e202301465) Gebhard Haberhauer and co-workers demonstrate that distances in macrocycles can be measured using a molecular spring and 13C-NMR spectroscopy. The sensitivity of the method even allows the determination of thermoelasticity at the molecular level: One studied system expands at low temperatures and shrinks at high temperatures.

确定溶液中纳米级距离是一个巨大的挑战。 Gebhard Haberhauer 及其同事在他们的研究文章 (e202301465) 中证明,可以使用分子弹簧和 13C-NMR 光谱来测量大环中的距离。该方法的灵敏度甚至可以在分子水平上测定热弹性:一种研究的系统在低温下膨胀,在高温下收缩。

16.A quasi-solid-state lithium-ion battery prepared by low-cost cellulose acetate exhibits extraordinary electrochemical stability, as reported by Lei Tian, Caizhen Zhu et al. in their Research Article (e202302767). The cellulose part in cellulose acetate is like a mountain forest. The esterified side groups are like the Great Wall built between the mountain forest, providing high-speed and stable transport channels for lithium ions.

Lei Tian、Caizhen Zhu 等人在他们的研究文章(e202302767)中报道,由低成本醋酸纤维素制备的准固态锂离子电池表现出非凡的电化学稳定性。醋酸纤维素中的纤维素部分就像山林。酯化侧基就像修筑在山林之间的长城,为锂离子提供高速稳定的传输通道。

17.Photocatalysis. The synthesis of a Z-scheme heterojunction TiO2/Ti-MOF-Pt with selectively anchored high-density Pt single-atomic cocatalysts for photocatalytic hydrogen evolution is reported by Chunshan Song, Xiang Wang, Xinwen Guo et al. in their Research Article (e202217439).

光催化。宋春山、王翔、郭新文等人在他们的研究文章(e202217439)中报道了具有选择性锚定高密度 Pt 单原子助催化剂的 Z 型异质结 TiO2/Ti-MOF-Pt 的合成,用于光催化析氢。

18.Glycan Engineering. In their Communication (e202303750), Yoshiyuki Manabe, Koichi Fukase et al. report a glycan-display approach that combines metabolic labeling and the glycan-caging strategy for editing cell-surface glycans. The method enables the introduction of antigen glycans onto cancer cells to induce immune responses.

聚糖工程。在他们的通讯 (e202303750) 中,Yoshiyuki Manabe、Koichi Fukase 等人。报告了一种聚糖展示方法,该方法结合了代谢标记和用于编辑细胞表面聚糖的聚糖笼蔽策略。该方法能够将抗原聚糖引入癌细胞以诱导免疫反应。

19.A methyltransferase from the green alga Chlamydomonas reinhardtii was identified and engineered for late-stage modifications of the carbon skeleton of terpenes. A variant with three changes in the amino acid sequence was able to produce methylated derivatives of linear terpenoids with high selectivity by C-methylation of an unactivated alkene. This opens new avenues for the modification of carbon scaffolds in various applications, as demonstrated by Bernhard Hauer et al. in their Communication (e202301601). Artwork: Verena Resch, Graz.

鉴定并改造了来自绿藻莱茵衣藻的甲基转移酶,用于萜烯碳骨架的后期修饰。氨基酸序列发生三个变化的变体能够通过未活化烯烃的 C-甲基化以高选择性产生线性萜类化合物的甲基化衍生物。正如 Bernhard Hauer 等人在他们的通讯(e202301601)中所证明的那样,这为碳支架在各种应用中的改性开辟了新途径。艺术品:Verena Resch,格拉茨。

20.Polydithioacetals , a new class of chemically recyclable thermoplastic and thermoset polymers, depolymerize to give a mixture of homologous macrocyclic monomers. Ying Yang and co-workers demonstrate in their Research Article (e202303039) that these monomers regenerate the virgin polymer via entropy-driven ring-opening polymerization with high conversions at ambient temperatures.

聚二硫缩醛是一类新型的可化学回收的热塑性和热固性聚合物,解聚后得到同系大环单体的混合物。 Ying Yang 及其同事在他们的研究文章 (e202303039) 中证明,这些单体通过熵驱动的开环聚合再生原始聚合物,在环境温度下具有高转化率。

21.Alkaline water electrolysis is a promising technology for hydrogen production, but the slow water dissociation process limits the kinetics of the hydrogen evolution reaction (HER). In their Research Article (e202300873), Emiliano Cortés and co-workers designed an atomically asymmetric local electric field using IrRu dizygotic single-atom sites (IrRu DSACs) to optimize the dissociation process by tuning the H2O adsorption configuration and orientation. As a result, IrRu DSACs exhibited an ultralow overpotential of 10 mV at 10 mA/cm2 current density in a single cell and a high stability over 300 h at 1 A/cm2 in a membrane electrode assembly.

碱性水电解是一种很有前途的制氢技术,但缓慢的水解离过程限制了析氢反应(HER)的动力学。在他们的研究文章 (e202300873) 中,Emiliano Cortés 及其同事使用 IrRu 双合单原子位点 (IrRu DSAC) 设计了原子不对称局部电场,通过调整 H2O 吸附构型和方向来优化解离过程。因此,IrRu DSAC 在单电池中在 10 mA/cm2 电流密度下表现出 10 mV 的超低过电位,在膜电极组件中在 1 A/cm2 电流密度下表现出超过 300 小时的高稳定性。

22.Dual-emissive triarylborane-based donor–π–acceptor fluorophores sensitive to environmental parameters, including temperature, solvent polarity, and viscosity of the medium, are reported by Shigehiro Yamaguchi and co-workers in their Research Article (e202303725). The intramolecularly coordinated B–X=P bond undergoes dissociation in the excited state, giving rise to bright emissions from the two different states. Precise tuning of the substituents led to single-molecule white emission in solution.

Shigehiro Yamaguchi 及其同事在他们的研究文章 (e202303725) 中报道了基于双发射三芳基硼烷的供体 - π - 受体荧光团对环境参数(包括温度、溶剂极性和介质粘度)敏感。分子内配位的 B–X=P 键在激发态下发生解离,从而从两种不同的状态产生明亮的发射。精确调节取代基可在溶液中产生单分子白色发射。

23.Electrocatalysis. In their Research Article (e202217815), Yangen Zhou, Zhongliang Tian, Yanqing Lai, Guihua Yu et al. report a nonequilibrium precipitation approach for the construction of a highly disordered crystal structure of layered double hydroxides as a model oxygen evolution catalyst.

电催化。 Yanen Zhou、Zhongliang Tian、Yanqing Lai、Guihua Yu 等人在他们的研究文章 (e202217815) 中报告了一种非平衡沉淀方法,用于构建层状双氢氧化物的高度无序晶体结构作为模型析氧催化剂。

24.Decoupled Artificial Photosynthesis.

解耦人工光合作用。

25.Ammonium Ion Batteries: Material, Electrochemistry and Strategy.

铵离子电池:材料、电化学和策略。

26.Transformation of an Imine Cage to a Covalent Organic Framework Film at the Liquid–Liquid Interface.

液-液界面处亚胺笼向共价有机框架膜的转变。

27.Apolipoprotein E Recognizes Alzheimer's Disease Associated 3-O Sulfation of Heparan Sulfate.

载脂蛋白 E 识别与硫酸乙酰肝素 3-O 硫酸化相关的阿尔茨海默病。

28.Formation and Loading of a (2S)-2-Ethylmalonamyl Starter Unit in the Assembly Line of Polyketide-Nonribosomal Peptide Hybrid Sanglifehrin A.

(2S)-2-乙基丙二酰胺起始单元在聚酮化合物-非核糖体肽杂交 Sanglifehrin A 装配线上的形成和装载。

29.Exclusive Co-N4 Sites Confined in Two-dimensional Metal-Organic Layers Enabling Highly Selective CO2 Electroreduction at Industrial-Level Current.

仅限于二维金属有机层中的独特 Co-N4 位点,可在工业级电流下实现高选择性 CO2 电还原。

30.Blended Conjugated Host and Unconjugated Dopant Polymers Towards N-type All-Polymer Conductors and High-ZT Thermoelectrics.

混合共轭主体和非共轭掺杂剂聚合物以实现 N 型全聚合物导体和高 ZT 热电体。

31.Palladium-Catalyzed Benzylic C(sp3)−H Carbonylative Arylation with Aryl Bromides.

钯催化的苯甲基 C(sp3)−H 与芳基溴的羰基化芳基化。

32.Molecule Saturation Boosts Acetylene Semihydrogenation Activity and Selectivity on a Core-Shell Ruthenium@Palladium Catalyst.

分子饱和可提高核壳钌@钯催化剂上的乙炔半氢化活性和选择性。

33.Enantioselective Rhodium-Catalyzed Pauson–Khand Reactions of 1,6-Chloroenynes with 1,1-Disubstituted Olefins.

1,6-氯炔与 1,1-二取代烯烃的对映选择性铑催化 Pauson-Khand 反应。

34.Nickel-Catalyzed Chemoselective Arylation of Amino Alcohols.

镍催化氨基醇的化学选择性芳基化。

35.Bio-inspired Structure-editing Fluorescent Hydrogel Actuators for Environment-interactive Information Encryption.

用于环境交互信息加密的仿生结构编辑荧光水凝胶致动器。

36.Light-Start CRISPR-Cas12a Reaction with Caged crRNA Enables Rapid and Sensitive Nucleic Acid Detection.

光启动 CRISPR-Cas12a 与笼状 crRNA 的反应可实现快速、灵敏的核酸检测。

37.An Iridium/Aluminum Cooperative Strategy for the β-C(sp3)-H Borylation of Saturated Cyclic Amines.

饱和环胺的 β-C(sp3)-H 硼基化的铱/铝合作策略。

38.Influence of Potassium Metal-Support Interactions on Dendrite Growth.

钾金属-载体相互作用对枝晶生长的影响。

39.A Tailored Versatile and Efficient NHC-Based NNC-Pincer Manganese Catalyst for Hydrogenation of Polar Unsaturated Compounds.

一种定制的多功能高效 NHC 基 NNC-Pincer 锰催化剂,用于极性不饱和化合物的氢化。

40.Reconstruction of Solid Electrolyte Interphase with SrI2 Reactivates Dead Li for Durable Anode-Free Li-Metal Batteries.

用 SrI2 重建固体电解质界面可重新激活耐用的无阳极锂金属电池的死锂。

41.Visible Light Conjugation with Triazolinediones as a Route to Degradable Poly(ethylene glycol)–Lipids for mRNA Lipid Nanoparticle Formulation.

可见光与三唑啉二酮偶联作为 mRNA 脂质纳米颗粒制剂中可降解聚乙二醇脂质的途径。

42.Crystallinity Regulation and Defects Passivation for Efficient and Stable Perovskite Solar Cells Using Fully Conjugated Porous Aromatic Frameworks.

使用完全共轭多孔芳香族框架实现高效稳定的钙钛矿太阳能电池的结晶度调节和缺陷钝化。

43.Conformationally Controlled sp3-Hydrocarbon-Based α-Helix Mimetics.

构象控制的 sp3-碳氢化合物基 α-螺旋模拟物。

44.Palladium-Catalyzed Inverse and Normal Dehydrogenative Aza-Morita–Baylis–Hillman Reactions with γ,δ-Unsaturated Compounds.

钯催化与 γ,δ-不饱和化合物的逆向和正向脱氢 Aza-Morita-Baylis-Hillman 反应。

45.A Hemilabile NHC-Gold Complex and its Application to the Redox Neutral 1,2-Oxyarylation of Feedstock Alkenes.

半稳定 NHC-金配合物及其在原料烯烃氧化还原中性 1,2-氧芳基化中的应用。

46.Noninvasive Early Diagnosis of Allograft Rejection by a Granzyme B Protease Responsive NIR-II Bioimaging Nanosensor.

通过颗粒酶 B 蛋白酶响应 NIR-II 生物成像纳米传感器对同种异体移植排斥进行无创早期诊断。

47.A Strong-Acid-Resistant [Th6] Cluster-Based Framework for Effectively and Size-Selectively Catalyzing Reductive Amination of Aldehydes with N,N-Dimethylformamide.

一种基于强酸[Th6]簇的框架,用于有效地和尺寸选择性地催化N,N-二甲基甲酰胺醛的还原胺化。

48.Non-symmetric Half-Fused B←N Coordinated Diketopyrrolopyrrole Building Block for n-type Semiconducting Polymers.

用于 n 型半导体聚合物的非对称半稠合 B←N 配位二酮吡咯并吡咯结构单元。

49.Electroreductive Dicarboxylation of Unactivated Skipped Dienes with CO2.

未活化的跳段二烯与 CO2 的电还原双羧化。

50.Ring-opening Polymerization of Enantiopure Bicyclic Ether-ester Monomers toward Closed-loop Recyclable and Crystalline Stereoregular Polyesters via Chemical Upcycling of Bioplastic.

通过生物塑料的化学升级改造,对映体纯双环醚酯单体开环聚合生成闭环可回收结晶立构聚酯。

51.Insight into the Molecular Mechanism for Enhanced Longevity of Supramolecular Vesicular Photocatalysts.

深入了解提高超分子囊泡光催化剂寿命的分子机制。

52.Inducing Covalent Atomic Interaction in Intermetallic Pt Alloy Nanocatalysts for High-Performance Fuel Cells.

诱导高性能燃料电池金属间铂合金纳米催化剂中的共价原子相互作用。

53.Synergizing Electron and Heat Flows in Photocatalyst for Direct Conversion of Captured CO2.

协同光催化剂中的电子流和热流,直接转化捕获的二氧化碳。

54.The Indenyl Effect: Accelerated C−H Amidation of Arenes via Ind*RhIII Nitrene Transfer Catalysis.

茚基效应:通过 Ind*RhIII 氮烯转移催化加速芳烃的 C−H 酰胺化。

55.Co0−Coδ+ Interface Double-Site-Mediated C−C Coupling for the Photothermal Conversion of CO2 into Light Olefins.

Co0−Coδ+ 界面双位点介导的 C−C 耦合,用于 CO2 光热转化为轻质烯烃。

56.Towards Automated Microfluidic-based Platforms: Optimizing Hydrogenation Efficiency of Nitrobenzene through π–π Interactions in Pd Nanoparticles on Covalent Organic Frameworks.

迈向基于微流体的自动化平台:通过共价有机框架上 Pd 纳米粒子的 π-π 相互作用优化硝基苯的氢化效率。

57.DNA-Based Artificial Receptors as Transmembrane Signal Transduction Systems for Protocellular Communication.

基于 DNA 的人工受体作为原细胞通讯的跨膜信号转导系统。

58.Diazabicyclic Electroactive Ionenes for Efficient and Stable Organic Solar Cells.

用于高效稳定有机太阳能电池的二氮杂双环电活性紫罗烯。

59.X-Ray-triggered Carbon Monoxide and Manganese Dioxide Generation based on Scintillating Nanoparticles for Cascade Cancer Radiosensitization.

基于闪烁纳米颗粒的 X 射线触发一氧化碳和二氧化锰生成,用于级联癌症放射增敏。

60.Rapid Phase Transitions of Thermotropic Glycolipid Quasicrystal and Frank-Kasper Mesophases: A Mechanistic Rosetta Stone.

热致糖脂准晶和 Frank-Kasper 中间相的快速相变:机械罗塞塔石碑。

61.Boosting the Efficiency of Dye-Sensitized Solar Cells by a Multifunctional Composite Photoanode to 14.13 %.

通过多功能复合光电阳极将染料敏化太阳能电池的效率提高至 14.13%。

62.Ambient Preparation of Benzoxazine-based Phenolic Resins Enables Long-term Sustainable Photosynthesis of Hydrogen Peroxide.

苯并恶嗪基酚醛树脂的常温制备可实现过氧化氢的长期可持续光合作用。

63.Aggregation-Induced Emission by Molecular Design: A Route to High-Performance Light-Emitting Electrochemical Cells.

分子设计的聚集诱导发射:高性能发光电化学电池的途径。

64.Manipulating Electric Double Layer Adsorption for Stable Solid-Electrolyte Interphase in 2.3 Ah Zn-Pouch Cells.

操纵双电层吸附以实现 2.3 Ah 锌袋电池中稳定的固体电解质界面。

65.Ultra-Permeable Dual-Mechanism-Driven Graphene Oxide Framework Membranes for Precision Ion Separations.

用于精密离子分离的超渗透双机制驱动氧化石墨烯框架膜。

66.Efficient Solar-osmotic Power Generation from Bioinspired Anti-fouling 2D WS2 Composite Membranes.

利用仿生防污二维 WS2 复合膜实现高效太阳能渗透发电。

67.Heterogeneous Photocatalytic Recycling of FeX2/FeX3 for Efficient Halogenation of C−H Bonds Using NaX.

FeX2/FeX3 的非均相光催化回收,利用 NaX 有效卤化 C−H 键。

68.Insight into Bioactivity of In-situ Trapped Enzyme-Covalent-Organic Frameworks.

深入了解原位捕获的酶共价有机框架的生物活性。

69.Assembly of One to Four As4 Analogues, (Ge2As2)2− or (Ge3As)3−, in the Coordination Sphere of [PhM]+, [MesM]+, or M2+ (M=Zn, Cd, Hg).

在 [PhM]+、[MesM]+ 或 M2+ (M=Zn、Cd、Hg) 配位范围内组装一到四个 As4 类似物 (Ge2As2)2− 或 (Ge3As)3−。

70.Time-dependent Phosphorescence Color of Carbon Dots in Binary Salt Matrices through Activations by Structural Confinement and Defects for Dynamic Information Encryption.

通过结构限制和动态信息加密缺陷的激活,二元盐基质中碳点的时间依赖性磷光颜色。

71.Automated Solid-Phase Oligo(disulfide) Synthesis.

自动化固相寡聚(二硫化物)合成。

72.Discovery of the Lanthipeptide Curvocidin and Structural Insights into its Trifunctional Synthetase CuvL.

兰西肽 Curvocidin 的发现及其三功能合成酶 CuvL 的结构见解。

73.Chemo-, Stereo- and Regioselective Fluoroallylation/Annulation of Hydrazones with gem-Difluorocyclopropanes via Tunable Palladium/NHC Catalysis.

通过可调钯/NHC 催化,腙与宝石二氟环丙烷进行化学、立体和区域选择性氟烯丙基化/环化。

74.Ruthenium-Catalyzed C−C Coupling of Terminal Alkynes with Primary Alcohols or Aldehydes: α,β-Acetylenic Ketones (Ynones) via Oxidative Alkynylation.

钌催化末端炔烃与伯醇或醛的 C−C 偶联:通过氧化炔基化生成 α,β-乙炔酮 (Ynones)。

75.Divergent Total Syntheses of (−)-Daphnezomines A and B and (+)-Dapholdhamine B.

(−)-Daphnezomines A 和 B 以及 (+)-Dapholdhamine B 的不同全合成。

76.Low Bandgap 2D Perovskite Single Crystal with Anomalous-large Charges/ions Collection Ratio for Ultra-sensitive and Stable X-ray Detectors.

低带隙二维钙钛矿单晶,具有异常大电荷/离子收集比,适用于超灵敏和稳定的 X 射线探测器。

77.Strong, Supertough and Self-Healing Biomimetic Layered Nanocomposites Enabled by Reversible Interfacial Polymer Chain Sliding.

通过可逆界面聚合物链滑动实现坚固、超韧和自修复仿生层状纳米复合材料。

78.Supramolecular Adhesives with Extended Tolerance to Extreme Conditions via Water-Modulated Noncovalent Interactions.

通过水调节非共价相互作用具有对极端条件的扩展耐受性的超分子粘合剂。

79.Construction of Axially Chiral Arylpyrroles via Atroposelective Diyne Cyclization.

通过天体选择性二炔环化构建轴向手性芳基吡咯。

80.Regulating Spin Polarization through Cationic Vacancy Defects in Bi4Ti3O12 for Enhanced Molecular Oxygen Activation.

通过 Bi4Ti3O12 中的阳离子空位缺陷调节自旋极化以增强分子氧活化。

81.A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes.

稳定多金属配合物中铀(II)和铀(I)合成子的途径。

82.Selective Photocatalytic Oxidative Coupling of Methane via Regulating Methyl Intermediates over Metal/ZnO Nanoparticles.

通过调节金属/ZnO 纳米粒子上的甲基中间体选择性光催化氧化偶联甲烷。

83.A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)nBu2] Template for Catalytic Hydrodefluorination of Perfluoroarenes.

用于催化全氟芳烃加氢脱氟的铑/二次氧化膦 [Rh/P(O)nBu2] 协同模板。

84.Selective Preparation of Phosphorus Mononitride (P≡N) from Phosphinoazide and Reversible Oxidation to Phosphinonitrene.

从叠氮膦选择性制备一氮化磷 (PeqN) 并可逆氧化为膦氮烯。

85.Multi-Site Conformational Exchange in the Synthetic Neomycin-Sensing Riboswitch Studied by 19F NMR.

通过 19F NMR 研究合成新霉素感应核糖开关中的多位点构象交换。

86.Structure- and Data-Driven Protein Engineering of Transaminases for Improving Activity and Stereoselectivity.

结构和数据驱动的转氨酶蛋白质工程,用于提高活性和立体选择性。

87.Visible-Light-Reactive Single-Chain Nanoparticles.

可见光反应单链纳米粒子。

88.Synthesis of Bicyclo[1.1.1]pentane (BCP)-Based Straight-Shaped Diphosphine Ligands.

基于双环[1.1.1]戊烷(BCP)的直形二膦配体的合成。

89.Inherently Emissive Puromycin Analogues for Live Cell Labelling.

用于活细胞标记的固有发射嘌呤霉素类似物。

90.Photoenzymatic Hydrosulfonylation for the Stereoselective Synthesis of Chiral Sulfones.

用于立体选择性合成手性砜的光酶氢磺酰化。

91.Passive Gate-Tunable Kinetic Photovoltage along Semiconductor-Water Interfaces.

沿半导体-水界面的无源栅极可调谐动态光电压。

92.Unveiling the Critical Role of Ion Coordination Configuration of Ether Electrolytes for High Voltage Lithium Metal Batteries.

揭示醚电解质离子配位构型对于高压锂金属电池的关键作用。

93.A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical Poly(quinoxaline-2,3-diyl).

基于单手螺旋聚(喹喔啉-2,3-二基)非键相互作用的无痕手性位移试剂。

94.Chemically Fueled Autonomous Sol→Gel→Sol→Gel→Sol Transitions.

化学燃料自主溶胶→凝胶→溶胶→凝胶→溶胶转变。

95.A Coordination Polymer of Vaska's Complex as a Heterogeneous Catalyst for the Reductive Formation of Enamines from Amides.

Vaska 配合物的配位聚合物作为酰胺还原形成烯胺的多相催化剂。

96.An Artificial Single Molecular Channel Showing High Chloride Transport Selectivity and pH-Responsive Conductance.

具有高氯离子传输选择性和 pH 响应电导的人工单分子通道。

97.A Fused [5]Helicene Dimer with a Figure-Eight Topology: Synthesis, Chiral Resolution, and Electronic Properties.

具有八字形拓扑的融合[5]螺旋烯二聚体:合成、手性拆分和电子特性。

98.Diphosphoryl-functionalized Polyoxometalates: Structurally and Electronically Tunable Hybrid Molecular Materials.

二磷酰基官能化多金属氧酸盐:结构和电子可调的杂化分子材料。

99.Air-Stable Organoradical Boron Reagents.

空气稳定的有机硼试剂。

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